Multifunctional Imidazole-Derived Polymeric Catalyst for Dephosphorylation Reactions Potentiated by Cationic and Anionic Micelles
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چکیده
منابع مشابه
Multifunctional Imidazole-Derived Polymeric Catalyst for Dephosphorylation Reactions Potentiated by Cationic and Anionic Micelles
Results confirm the catalytic potential of imidazole groups anchored on the polymeric backbone of polyvinylimidazole (PVI) in dephosphorylation reactions with diand tri-phosphoesters, promoting impressive enhancements up to 10-fold. We propose the imidazole groups on PVI react by nucleophilic catalysis (neutral specie) with a phosphate triester and bifunctionally by general acid-nucleophilic ca...
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ژورنال
عنوان ژورنال: Journal of the Brazilian Chemical Society
سال: 2015
ISSN: 0103-5053
DOI: 10.5935/0103-5053.20150228